Improve sampling and detection of carbonyls in air

Achieve sensitive and reliable results with air sampling media for a wide range of applications in various configurations for solvent desorption, thermal desorption, passive and whole air sampling from Supelco. Ensure low background for carbonyl sampling with products that are produced to the highest quality standards in a carbonyl controlled manufacturing environment that is complemented by high-purity solvents and calibration standards.

The sampling of aldehydes and ketones requires an on-site derivatization on a coated adsorbent e.g. with 2,4-dinitrophenylhydrazine (2,4-DNPH). Supelco's product range includes the low back pressure DNPH (LpDNPH) cartridges (available in 6 different configurations and 16 products) for active sampling, which ensure longer pump operation, glass tubes (ORBO™) and DNPH coated filters as well as devices with otherwise coated adsorbents for sampling carbonyls.

Our product range is suitable for OSHA, NIOSH, ASTM, EPA and CARB methods. For a complete overview on air monitoring from Sigma-Aldrich, visit SigmaAldrich.com/air-monitoring.

LpDNPH Products

LpDNPH cartridges are air sampling devices designated for sampling carbonyls (e.g. formaldehyde) in ambient, indoor and industrial atmospheres. Carbonyls are trapped on a high-purity adsorbent coated with 2,4-dinitrophenylhydrazine where they are converted to hydrazone derivatives. The derivatives are eluted from the cartridge with acetonitrile and analyzed by HPLC, in most cases. Select LpDNPH products are vacuum packaged in our low-background storage bag to ensure purity. DNPH

Method Applications

US EPA IP-6A – Determination of Formaldehyde & Other Aldehydes

US EPA TO-11A – Method for Determination of Formaldehyde in Ambient Air Using Adsorbent Cartridge Followed by HPLC

US EPA 100 – Sampling for Formaldehyde & Other Carbonyl Compounds

ASTM Method D5197 – Standard Test Method forDetermination of Formaldehyde and Other Carbonyl Compounds

NIOSH 2016 – Formaldehyde

NIOSH 2532 – Glutaraldehyde

NIOSH 2539 – Aldehydes, Screening

NIOSH 2541 – Formaldehyde by GC

NIOSH 3500 – Formaldehyde by VIS; Impinger Method

OSHA 52 – Acrolein and/or Formaldehyde

OSHA 64 – Glutaraldehyde

OSHA 81 – Crotonaldehyde

OSHA 85 – Valeraldehyde